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41.
Consistent calculation of fugacities of fluid mixtures remains as one of the most important subjects in contemporary molecular
thermodynamics. In practice, equations of state (EOSs) and gE-models have been used. However, most EOSs are erroneous for condensed phases at high densities and gE-models are inapplicable for pressuresensitive systems. Recently to remedy the shortcomings in both approaches, there has
been a surge of new gE-EOS mixing rules. By equating any set of EOS and gE-models, the limitations in both approaches could be resolved significantly. However, the self-consistency in the underlying
concept of those mixing rules remains controversial. During the last several years, the present authors proposed a new lattice-fluid
EOS and its simplification relevant to phase equilibrium calculations. Without employing any gE-EOS mixing rule and with only two parameters for a pure component and one adjustable interaction energy parameter for a binary
mixture, results obtained to date demonstrated that the EOSs are quantitatively applicable to a great variety of phase equilibrium
properties of mixtures, especially, for complex and/or macromolecular systems. In the present article we summarize the EOSs
and extended the applications to liquid-liquid Equilibria. In part I, we discussed briefly the molecular thermodynamic aspects
of general derivation of the EOS and a brief discussion of applying the EOSs to pure fluids while the illustrative application
to various real mixture systems is discussed in part II. 相似文献
42.
在连铸生产铝镇静钢时,水口絮流一直是困扰工程技术人员的一个难题.从絮流的原因入手,分析了Al2O3生成的控制.并介绍了几种钢水钙化的方法,从中比较出用复合造渣材料来解决浇铸铝镇静钢的优点. 相似文献
43.
A. Forcellese L. Fratini F. Gabrielli F. Micari 《Journal of Materials Processing Technology》1996,60(1-4):225-232
The effects of the punch nose radius and sheet thickness on the elastic springback and residual stresses in the 90° V-punch and U-die bending process of AA 5083 aluminium alloy have been extensively studied by numerical simulations based on the finite element method. The results show that, irrespective of the sheet thickness and punch stroke, the springback ratio is not affected by the punch nose radius. Such results are in excellent agreement with the experimental ones obtained in similar conditions. As far as punch nose radius effects on the residual stresses are considered, significant differences were observed between residual stresses predicted with different nose radii. In particular, the shifting of the neutral layer and increase in the magnitude of the residual stresses predicted by the FEM code were found with decreasing punch nose radius. 相似文献
44.
乙炔在磁稳定床中的选择性加氢研究 总被引:1,自引:0,他引:1
制备了一种磁性Pd/Al2O3催化剂,采用磁稳定床考察了活性组分负载量、反应条件及CO浓度对乙炔加氢反应性能的影响。结果表明,当反应温度80℃、反应压力1.5MPa、空速9000h-1、磁场强度(H)25kA/m时,乙炔转化率为100%,乙烯选择性可达81%,具有优良的乙炔加氢活性和乙烯选择性,优于相同反应条件下的进口催化剂;250h稳定性实验结果表明,磁性Pd/Al2O3催化剂具有良好的初活性和乙烯选择性,催化剂性能稳定。 相似文献
45.
对耐火材料——棕刚玉粉的质量分析控制,提出了用实用性的检测方法测定其Al2O3含量。通过与国家标准分析方法的对比试验,证实快速实用分析方法测定棕刚玉粉中Al2O3含量是可行的。 相似文献
46.
Two-phase (B2+L12) nickel aluminide intermetallic compounds were synthesized by the pressure-assisted volume combustion synthesis (CS). The production and characterization of the samples containing NiAl+Ni3Al were investigated. Aluminum (99% pure, 15 μm) and carbonyl nickel (99.8 pure, 4-7 μm) powders were used. The production of intermetallic compound was carried out at 1050 °C under 150 MPa uniaxial pressure in open air atmosphere in an electrical resistance furnace for 60 min. The formation temperature of intermetallic compound was determined by differential scanning calorimeter (DSC) analysis, and exothermic temperature of powder mixture was determined as 653 °C. The characterization of samples was confirmed by optical microscope, SEM and XRD analysis. It was observed that the structure of compound has very low porosity and the formation of NiAl was completed successfully. The relative density of test materials measured according to Archimedes’ principle was 98.04%. The microhardness of test materials was about 351 HVN1. 相似文献
47.
深部调剖驱油交联剂的研究 总被引:3,自引:0,他引:3
为提高非均质性严重的地层原油采出率 ,合成了用于聚合物驱油的 4种交联剂 ,并对聚合物种类、用量和其与交联剂组成的体系进行了评价。 4 0℃下铝交联剂凝胶粘度低 ,酚醛树脂交联剂低温下不成胶 ,而有机铬交联剂 (J2 )和有机复合胺 (J3)交联效果好。当选用HPAM/有机铬交联剂 /有机酸交联体系时 ,其中HPAM相对分子质量为 2 1× 10 7,可通过改变体系pH值调节成胶速度 ,pH值 6 5时 ,14 0 0mg/LHPAM和 4 0 0mg/LJ2组成的体系在 4 0℃、30d可形成粘度为12 0mPa·s以上的凝胶 ,且热稳定性好 ,成胶时间能满足现场施工需要。 14 0 0mg/LHPAM和10 0 0mg/LJ3交联剂组成的体系 ,成胶时间长 ,有利于油田深部调剖驱油 相似文献
48.
Influence of Ni Interlayers on the Mechanical Properties of Ti6Al4V/(WC-Co) Friction Welds 总被引:2,自引:0,他引:2
M. Shamanian M. Salehi A. Saatchi T. H. North 《Materials and Manufacturing Processes》2003,18(4):581-598
Ni interlayers were introduced prior to dissimilar friction welding of Ti6Al4V base material to three cemented carbide substrates. The fracture strength of Ti6Al4V/(WC-6 wt% Co) welds were poor and were markedly improved when 20-µm thick Ni interlayers were introduced prior to dissimilar friction welding. These results were only produced when the (WC-6 wt% Co) cermet was electroplated prior to friction welding. When the Ti6Al4V alloy was electroplated prior to friction welding, fractured WC particles and cracking were observed in the (WC-Co) carbide substrate. The fracture strengths of Ti6Al4V/(WC-11 wt% Co) and Ti6Al4V/(WC-24 wt% Co) welds were not improved when 20-µm thick Ni interlayers were introduced prior to friction welding. During mechanical testing, the Ni layer retained at the dissimilar joint interface created a region of weakness. 相似文献
49.
探讨了试样先灼烧除碳,再加混合熔剂副熔,盐酸溶液中浸取,采取氟盐置换法,测定铝镁碳砖中三氧化二铝,终点易于判断,结果令人满意。 相似文献
50.